H2S retention with Ca-based sorbents in a pressurized fixed- bed reactor: application to moving-bed design

The H2S retention with Ca-based sorbents in a pressurized fixed-bed reactor (1 MPa) has been analyzed, obtaining the breakthrough curves with a dolomite and two different limestones, different particle size (+0.8-1.0 mm, +1.25-1.6 mm, and +1.6-2.0 mm), and both at calcining (1173 K) and non-calcining conditions (1123 K). The effect of the stoichiometric time in the breakthrough curves has been analyzed varying the bed length, the gas velocity and the sorbent fraction in the bed. From these results, the conversion and H2S concentration profiles in the transition zone and the length of unused bed (LUB) have been determined. H2S retention in fixed-bed until concentration close to the given by the thermodynamic equilibrium was obtained using dolomite or limestone at calcining conditions, and dolomite at non-calcining conditions. The results of H2S retention in a fixed-bed reactor has been applied to the calculus of the minimum height of a countercurrent moving-bed reactor to obtain the maximum H2S retention with the minimum amount of sorbent. A mathematical model was developed to predict the experimental results obtained in the fixed-bed reactor, which was also valid for the design of countercurrent moving-bed reactors for gas desulphurization.